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Successfully complete Musou mode with a character from the Wu, Shu, Wei, and Other factions.

Successfully complete Musou mode to unlock the Master ddifficulty for Musou mode and Free mode.

Complete the indicated task to unlock the corresponding character.

Character - Task to be completed
Cao Cao - Complete Musou mode with three Wei characters.
Cao Pi - Defeat Cao Pi in less than five minutes on the Wu side of He Fei.
Cao Ren - Complete Battle Objective 2 on the Lu Bu side of Fan Castle.
Diao Chan - Complete Musou mode with one character from each kingdom.
Dong Zhuo - Complete Musou mode as Lu Bu.
Gan Ning - Complete Musou mode as a Wu character.
Guan Ping - Complete Battle Objective 2 on the Shu side of Fan Castle and finish the battle with Guan Ping surviving.
Huang Gai - Complete Battle Objective 3 on the Wu side of The Battle of Chi Bi.
Huang Zhong - Complete Battle Objective 1 on the Wei side of Ding Jun Mountain.
Ling Tong - Complete Battle Objective 1 on the Wei side of the Battle of Shi Ting.
Liu Bei - Complete Musou mode with three Shu characters.
Lu Bu - Complete Musou mode with Liu Bei, Cao Cao, and Sun Jian.
Lu Meng - Complete Battle Objective 2 on the Wei side of He Fei.
Ma Chao - Complete Battle Objective 2 on the Wei side of Han Zhong Attack Defense Battle.
Pang Tong - Complete Battle Objective 3 at Cheng Du battle and finish the battle with Pang Tong surviving.
Sun Ce - Complete Battle Objective 1 on the Sun Jian side of the Battle of Xia Pi.
Sun Jian - Complete Musou mode with three Wu characters.
Sun Quan - Complete Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi.
Taishi Ci - Defeat Taishi Ci in the Battle For Wu Territory.
Wei Yan - Complete Battle Objective 2 on the Shu side of Wu Zhang Plains and finish the battle with Wei Yan surviving.
Xiahou Yuan - Complete Battle Objective 1 on the Shu side of Ding Jun Mountain.
Xiao Quio - Complete Battle Objective 3 on the Wu side of the Battle of Shi Ting.
Xu Chu - On He Fei on the Wu side, personally kill Cao Ren and Xu Chu.
Xu Huang - Complete Battle Objective 2 on the Wei or Wu side of Fan Castle.
Yue Ying - Complete Battle Objective 1 on the Wei side of the Battle of Wu Zhang Plains.
Zhang Jiao - Defeat Zhang Jiao in the Yellow Turban Rebellion.
Zhang Liao - Complete Musou mode as a Wei character.
Zheng He - Complete Battle Objective 2 on the Shu side of Han Zhong Attack Defense Battle.
Zhou Tai - Complete Battle Objective 3 on the Shu side of Yi Ling.
Zhuge Liang - Complete Musou mode with a Shu character.